Starting from Skype 4, we can run multiple instances of Skype. To do that, just pass /secondary argument to the skype.exe, just like this:
It will then run the 2nd instance of Skype and so on.
If you don’t like using command line tool you can make a shortcut for it as explained in this blog post:
http://www.axelsegebrecht.com/how-to/run-multiple-instances-of-skype/
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